# Thoughts of Chair-man Moire

My apples and orange peels question, Sy,  isn’t that the same as Jeremy’s?  What’s the connection between heat capacity and counting?”

“You’re right, Anne.  Hmm.  Say, Al, all your coffee shop tables came with four chairs apiece, right?”

“Yup, four-tops every one, even in the back room.”

“You neaten them all up, four to a table, in the morning?”

“The night before.  There’s never time in the morning, customers demand coffee first thing.”

“But look, we’ve got six people seated at this table.  Where’d the extra chairs come from?”

“Other tables, of course.  Is this going somewhere?”

“Almost there.  So in fact the state of the room at any time will have some random distribution of chairs to tables.  You know on the average there’ll be four at a table, but you don’t know the actual distribution until you look, right?”

“Hey, we’re counting again.  You’re gonna say that’s about entropy ’cause the difference between four at a table and some other number is all random and there’s some formula to calculate entropy from that.”

“True, Vinnie, but we’re about to take the next step.  How did these chairs wind up around this table?”

“We pulled them over, Mr. Moire.”

“My point is, Jeremy, we spent energy to get them here.  The more chairs that are out of position — ”

“The higher the entropy, but also the more energy went into the chairs.  It’s like that heat capacity thing we started with, the energy that got absorbed rather than driving the steam engine.”

“Awright, Anne!” from Jeremy <Jennie bristles a bit>, “and if all the chairs are in Al’s overnight position it’s like absolute zero.  Hey, temperature is average kinetic energy per particle so can we say that the more often a chair gets moved it’s like hotter?”

Jennie breaks in.  “Not a bit of it, Jeremy!  The whole metaphor’s daft.  We know temperature change times heat capacity equals the energy absorbed, right, and we’ve got a link between energy absorption and entropy, right, but what about if at the end of the day all the chairs accidentally wind up four at a table?  Entropy change is zero, right, but customers expended energy moving chairs about all day and Al’s got naught to set straight.”

“Science in action, I love it!  Anne and Jeremy, you two just bridged a gap it took Science a century to get across.  Carnot started us on entropy’s trail in 1824 but scientists in those days weren’t aware of matter’s atomic structure.  They knew that stuff can absorb heat but they had no inkling what did the absorbing or how that worked.  Thirty years later they understood simple gases better and figured out that average kinetic energy per particle bit.  But not until the 1920s did we have the quantum mechanics to show how parts of vibrating molecules can absorb heat energy stepwise like a table ‘absorbing’ chairs.  Only then could we do Vinnie’s state-counting to calculate entropies.”

“Yeah, more energy, spread across more steps, hiding more details we don’t know behind an average, more entropy.  But what about Jennie’s point?”

“Science is a stack of interconnected metaphors, Vinnie.  Some are better than others.  The trick is attending to the boundaries where they stop being valid.  Jennie’s absolutely correct that my four-chair argument is only a cartoon for illustrating stepwise energy accumulation.  If Al had a billion tables instead of a dozen or so, the odds on getting everything back to the zero state would disappear into rounding error.”

“How does black hole entropy play into this, Sy?”

“Not very well, actually.  Oh, sure, the two systems have similar structures.  They’ve each got three inter-related central quantities constrained by three laws.  Here, I’ve charted them out on Old Reliable.”

“OK, their Second and Third Laws look pretty much the same, but their First Laws don’t match up.”

“Right, Al.  And even Bekenstein pointed out inconsistencies between classic thermodynamic temperature and what’s come to be called Hawking temperature.  Hawking didn’t agree.  The theoreticians are still arguing.  Here’s a funny one — if you dig deep enough, both versions of the First Law are the same, but the Universe doesn’t obey it.”

“That’s it, closing time.  Everybody out.”

~~ Rich Olcott

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# Rockin’ Round The Elephant

<continued…>  “That’s what who said?  And why’d he say that?”

“That’s what Hawking said, Al.  He’s the guy who first applied thermodynamic analysis to black holes.  Anyone happen to know the Three Laws of Thermodynamics?”

Vinnie pipes up from his table by the coffee shop door.  “You can’t win.  You can’t even break even.  But you’ll never go broke.”

“Well, that’s one version, Vinnie, but keep in mind all three of those focus on energy.  The First Law is Conservation of Energy—no process can create or destroy energy, only  transform it, so you can’t come out ahead.  The Second Law is really about entropy—”

“Ooo, the elephant!”

“Right, Anne.  You usually see the Second Law stated in terms of energy efficiency—no process can convert energy to another form without wasting some of it. No breaking even.  But an equivalent statement of that same law is that any process must increase the entropy of the Universe.”

“The elephant always gets bigger.”

“Absolutely.  When Bekenstein and Hawking thought about what would happen if a black hole absorbed more matter, worst case another black hole, they realized that the black hole’s surface area had to follow the same ‘Never decrease‘ rule.”

“Oh, that Hawking!  Hawking radiation Hawking!  The part I didn’t understand, well one of the parts, in that “Black Holes” Wikipedia article!  It had to do with entangled particles, didn’t it?”

“Just caught up with us, eh, Jeremy?  Yes, Stephen Hawking.  He and Jacob Bekenstein found parallels between what we can know about black holes on the one hand and thermodynamic quantities on the other.  Surface area and entropy, like we said, and a black hole’s mass acts mathematically like energy in thermodynamics.  The correlations were provocative ”

“Mmm, provocative.”

“You like that word, eh, Anne?  Physicists knew that Bekenstein and Hawking had a good analogy going, but was there a tight linkage in there somewhere?  It seemed doubtful.”

“Nothin’ to count.”

“Wow, Vinnie.  You’ve been reading my posts?”

“Sure, and I remember the no-hair thing.  If the only things the Universe can know about a black hole are its mass, spin and charge, then there’s nothing to figure probabilities on.”

“Exactly.  The logic sequence went, ‘Entropy is proportional to the logarithm of state count, there’s only one state, log(1) equals zero,  so the entropy is zero.’  But that breaks the Third Law.  Vinnie’s energy-oriented Third Law says that no object can cool to absolute zero temperature.  But an equivalent statement is that no object can have zero entropy.”

“So there’s something wrong with black hole theory, huh?”

“Which is where our guys started, Vinnie.  Being physicists, they said, ‘Suppose you were to throw an object into a black hole.  What would change?’

“Its mass, for one.”

“For sure, Jeremy.  Anything else?”

“It might not change the spin, if you throw right.”

“Spoken like a trained baseball pitcher.  Turns out its mass governs pretty much everything about a black hole, including its temperature but not spin or charge.  Once you know the mass you can calculate its entropy, diameter, surface area, surface gravity, maximum spin, all of that.  Weird, though, you can’t easily calculate its volume or density — spatial distortion gets in the way.”

“So what happens to all those things when the mass increases?”

“As you might expect, they change.  What’s interesting is how each of them change and how they’re linked together.  Temperature, for instance, is inversely proportional to the mass and vice-versa.  Suppose, Jeremy, that you threw two big rocks, both the same size, into a black hole.  The first rock is at room temperature and the other’s a really hot one, say at a million degrees.   What would each do?”

“The first one adds mass so from what you said it’d drop the temperature.  The second one has the same mass, so I don’t see, wait, temperature’s average kinetic energy so the hot rock has more energy than the other one and Einstein says that energy and mass are the same thing so the black hole gets more mass from the hot rock than from the cold one so its temperature goes down … more?  Really?”

“Yup.  Weird, huh?”

“How’s that work?”

“That’s what they asked.”

~~ Rich Olcott