A Big Purple Snowball

Cathleen’s back at the mic. “Okay, folks, now for the third speaker in tonight’s Crazy Theory seminar. Kareem, you have the floor.”

“Thanks, Cathleen. Some of you already know I do old‑rock geology. If a rock has a bone in it, I’m not interested. Paleontology to me is like reading this morning’s newspaper. So let me take you back to Precambrian times when Earth may have been purple.”

Kareem’s a quiet guy but he’s got the story‑teller’s gift, probably honed it at field expedition campfires, so we all settle back to listen.

“Four and a half billion years ago, Earth was bright orange. That’s not the color it reflected, that’s the color it glowed. You’ve all seen glass‑blowers at work, how the material gives off a bright orange light coming out of the flame or furnace, soft and ready to be formed. That’s what the planet’s surface was like after its Moon‑birthing collision with Theia. Collisions like that release so much heat that there’s no rocks, just layers of smooth molten glassy slag floating on fluid silicates and nickel‑iron like in a blast furnace. No atmosphere, all the volatiles have been boiled off into space. Got the picture?”

General nodding, especially from maybe‑an‑Art‑major who’s good at pictures.

“Time passes. Heat radiating away cools the world from the outside inward. Now the surface is a thin glassy cap, black like obsidian and basalt, mostly smooth. The cooling contracting cap fractures from the tension while the shrinking interior pulls inward, slow but not gentle. The black glassy surface becomes low craggy mountains and razor‑rubble, sharp enough to slice hiking boots to ribbons. There’s no erosive wind or water yet to round things off. Everything stays sharp‑edged.”

Voice from the back of the room — “Where’s our water from then?”

“Good question. Could be buried water that never got the chance to escape past the cap, could be water ferried in on icy comets or worldlets. People argue about it and I’m not taking sides. The planet gets a new color after it cools enough to hold onto water molecules however they got there — but that water doesn’t stay on the surface. Raindrops hitting still‑hot rock hiss back into steamy clouds. If you were on the moon at the time you’d see a white‑and‑grey Earth like Jupiter’s curdled cloud-tops. Visualize a series of million‑year Hurricane Debbies, all over the world.”

He pauses to let that sink in.

“When things finally cool down enough to allow surface water there’s oceans, but they’re not blue. Millions of years of wind and water erosion have ground the sharp rubble to spiky dust. Most of the thrust‑raised mountains, too. Much of the dust is suspended or dissolved in the ocean turning it black. For a while. The dust is loaded with minerals, especially sulfides, very nutritious for a group of not‑quite bacteria called Archaea that eat sulfides using a molecule that’s powered by green light but reflects red and blue. When the Archaea take over, the oceans look magenta from the reflected red and blue.”

Maybe‑an‑Art‑major giggles.

“Next major event, we think, was the Huronian Glaciation, when most or all of the Earth was a solid white because it was covered with ice. Killed off most or the Archaea. When that melted, different parts of the ocean turned black from floating dead Archaea and and then milky turquoise from sulfur particles. Next stage was purple, from a different group of sulfur‑eating purple almost‑bacteria. Then we had snowball whiteness again, which gave green‑reflecting chlorophyll‑users a chance to take over, clear our the sulfur and leave the oceans blue.”

VBOR — “That’s your Crazy Theory?”

“No, that’s mostly mainstream. Question is, what terminated the deepfreezes? Lots of ideas out there — solar dimming and brightening, different combinations of CO2 and methane from volcanoes or bacteria, even meteorites. Anyone remember Ian Malcom’s repeated line in the Jurassic Park movies?”

Everyone — “Life will find a way!”

“Right on. My crazy’s about the two almost‑bacteria. Suppose each kind managed to infiltrate their day’s Great Extinction glaciers. Suppose planet‑wide bacterial purple pigments absorbed sunlight’s energy, melting the ice. Karma, yes?”

~ Rich Olcott

To Fly on Another World

“Uncle Sy, why is PV=nRT the Ideal Gas Equation? Is it because it’s so simple but makes sense anyway?”

“It is ideal that way, Teena, but it’s simply an equation about gases that are ideal. Except there aren’t any. Real gases come close but don’t always follow the rule.”

“Why not? Are they sneaky?”

“Your kind of question. We like to think of gas particles as tiny ping‑pong balls that just bounce off of each other like … ping‑pong balls. That’s mostly true most of the time for most kinds of gas. One exception has to do with stickiness. Water’s one of the worst cases because its H2O molecules like to chain up. When two H2Os collide, if they’re pointed in the right directions they share a hydrogen atom like a bridge and stick together. If that sort of stickiness happens a lot then the quantity measure n acts like it’s less than we’d expect. That makes the PV product smaller.”

“I bet that doesn’t happen much when the gas is really hot. Two particles might stick and then BANG! another particle hits ’em and breaks it up!”

“Good thinking and that’s true. But there’s another kind of exception that holds even at high temperatures. A well‑behaved gas is mostly empty space because the ping‑pong balls are far apart unless they’re actually colliding. But suppose you squeeze out nearly all of the empty space and then try to squeeze some more.”

“Oh! The pressure gets even bigger than the equation says it should because you can’t squeeze the particles any smaller than they are, right?”

“Exactly.”

“Well, if the equation has these problems, why do we even use it at all?”

“Because it’s good enough, enough of the time, and we know when not to use it. I’ll give you an example. One of my clients wanted to know air density at ground level on Saturn’s moon Titan and all the planets that have an atmosphere.” <showing Old Reliable’s screen> “I found the planet data I needed in NASA’s Planetary Science website, but I had to do my own calculation for Titan. The pressure’s not crazy high and the temperature’s chilly but not quite cold enough to liquify nitrogen so the situation’s in‑range for the Ideal Gas Equation.”

“What’s a Pa?”

“That’s the symbol for a pascal, the unit of pressure. kPa is kilopascals, just like kg is kilograms. Earth’s atmospheric pressure is about 100 kPa.”

“Reliable says Wikipedia says Titan’s air is mostly nitrogen like Earth’s air is. Titan’s just a moon so it has to be smaller than Earth so its gravity must be smaller, too. Why is its atmosphere so much denser?”

“The cold. Titan’s air is 200 kelvins colder than Earth’s average temperature. You’re right, an individual gas particle feels a smaller pull of gravity on Titan, but it doesn’t have much kinetic energy to push its neighbors away so they all crowd closer together.”

“Why in the world does your client want to know that density number?”

“Clients rarely give me reasons. I suspect this has to do with designing a Titan‑explorer aircraft.”

“Ooo! Wait, what does that have to do with air density?”

“It has to do with how hard the machine has to work to push itself up. It’ll probably have horizontally spinning blades that push the air downwards, like helicopters do. With a setup like that, the lift depends on the blade’s length, how fast it’s spinning, and how dense the air is. If the air is dense, like on Titan, the designers can get the lifting thrust they need with short blades or a slow spin. On Mars the density’s only 2% of Earth’s so Ingenuity‘s rotors were 4 feet across and spun about ten times faster than they’d have to on Earth.”

“What about on our helium‑oxygen Earth?”

“That’s pretty much the same calculation. Give me a sec.” <tapping on Old Reliable’s screen> “Gas density would be a tenth of Earth’s, but a HeO‑copter would have to work against full‑Earth gravity. Huge blades rotating at supersonic speeds. Probably not a practical possibility.”

“Aw.”

“Yeah.”

~ Rich Olcott

The Ideal Gas Game

“But Uncle Sy, you never did answer my real question!”

“What question was that, Teena?”

“About the helium planet. With oxygen. Oh, I guess I never did get around to asking that part of it. You side‑tracked us into how a helium‑oxygen atmosphere would be unstable unless it was really cold or the planet had more gravity than Earth so the helium wouldn’t fly away. But what I wanted to know was, what would it be like before the helium left? Like, could we fly a plane there?”

“Mmm, let’s get a leetle more specific. You asked about swapping all of Earth’s atmospheric nitrogen with helium. Was that one helium atom for each nitrogen molecule or each nitrogen atom?”

“What difference would that make?”

“Mass, to begin with. A helium atom weighs about 1/3 of a nitrogen atom, 1/7 of a nitrogen molecule. The atmospheric pressure we feel is the weight of all the air molecules above us. Swap out 80% of those molecules for something lighter, pressure goes down whether we swap helium for molecules or helium for atoms. We could calculate either one. But the change would be much harder to calculate for the atom‑for‑atom swap.”

“Why?”

“Mmm, have you gotten into equations yet in school?”

“You mean algebra, like 3x+7=8x+2? Yeah, they’re super‑easy.”

“This won’t even be as complicated as that. Here’s a famous Physics equation called The Ideal Gas Law — PV=nRT. Each letter stands for one quantity. Two adjacent quantities are multiplied together, okay? The pressure in a container is P, the container’s volume is V, T is the absolute temperature, and n is a measure of how much gas is in there.”

“You skipped R.”

“Yes, I did. It’s a constant number. Its job is to make all the units come out right. For instance, if the pressure’s in atmospheres, the volume’s in liters, n is in grams of helium and the temperature is in kelvins, then R is 0.021. Suppose you’re holding a balloon filled with helium and it’s at room temperature. What can you say about the gas?”

“Umm, all the nRT stuff doesn’t change so P times V, whatever it is, doesn’t change either.”

“If we let it fly upward until the pressure was only half what it is here…?”

“Then V would double. The balloon would get twice as big. Unless it burst, right?”

“You got the idea. Okay, now let’s fiddle with the right-hand side. Suppose we double the amount of helium.”

P times V must get bigger but we don’t know which one.”

“Why not both?”

“Wooo… Each one could get some bigger… Oh, wait, I’m holding the balloon so the pressure’s not going to change so the balloon gets twice bigger.”

“Good thinking. One more thing and we can get back to your difference question. The Ideal Gas Law doesn’t care what kind of gas you’re working with. All the n quantity really cares about is how many particles are in the gas. A particle can be anything that moves about independently of anything else — helium atom or nitrogen molecule, doesn’t matter. If you change the definition of what n is measuring, all that happens is you have to adjust R so the units come out right. Then the equation works fine. Next step—”

“Wait, Uncle Sy, I want to think this atom‑or‑molecule thing through for myself. I’m gonna ignore R times T because both of them stay the same. So if we swap one atom of helium for one molecule of nitrogen, the number of particles doesn’t change and PV doesn’t change. But if we swap one atom of helium for each atom of nitrogen then n doubles and so does PV. But if we do that for the whole atmosphere then we can’t say that the pressure won’t change because the atmosphere could just expand and that’s the V but the pressures are all different as you go higher up anyway. Oh, wait, T changes, too, because it’s cold up there. It’s complicated, isn’t it?”

“It certainly is. Can we stick to just the simple atom‑for‑molecule swap?”

“Uh‑huh.”

~~ Rich Olcott

  • Thanks again, Xander, and happy birthday. Your question was deeper than I thought.

A Fleeting Shadowed Sky

“Hey, Uncle Sy, I’ve got a what‑if for you.”

“What’s that, Teena?”

“Suppose we switched Earth’s air molecules with helium. No, wait, except for the oxygen molecules. I know we need them.”

“First off, a helium-oxygen atmosphere wouldn’t last very long, not on the geological time scale. That’s an unstable situation.”

“Why, would the helium burn up like I’ve seen hydrogen do?”

“No, helium doesn’t burn. Helium atoms are smug. They’re happy with exactly the electrons they have. They don’t give, take or share electrons with oxygen or anything else. No, the issue is that helium’s so light.”

“What difference does that make?”

“The oxygen and helium won’t stay mixed together.”

“The air’s oxygen and nitrogen molecules are all mixed together. They told us that in Science class.”

“That’s correct. But oxygen and nitrogen molecules weigh nearly the same. It would take eight balloon‑fulls of helium to match the weight of one balloon‑full of oxygens. Suppose you had a bunch of equal‑weighted marbles, say red ones and blue ones. Pretend you pour them into a big bucket and stir them around like an atmosphere does. Which color would wind up on top?”

“Both, they’d stay mixed together.”

“Uh-huh. Now replace the blue marbles with marble‑sized ping‑pong balls and stir well.”

“The heavy marbles slide to the bottom. The light balls need to be somewhere so they get bullied up to the top.”

“Exactly. That’s what the oxygen molecules would do — sink down toward the ground and shove the helium atoms up to the top of the atmosphere. Funny thing though — the shoving happens faster than the sinking.”

“Why’s that?”

“It’s the mass thing again. At any given temperature, helium atoms in a gas zip around four times faster than oxygen molecules do. Anyway, the helium atoms that arrive up top won’t stay there.”

“Where else would they go?”

“Anywhere else, basically. Have you heard the phrase, ‘escape velocity‘?”

“It has something to do with rockets, doesn’t it?”

“Well, them, too. The general idea is that once you reach a certain threshold speed relative to a planet or something, you’re going too fast for its gravity to pull you back down. There’s a formula for calculating the speed. The fun thing is, the speed depends on the mass of what you’re escaping from and your distance from the object’s center, but it doesn’t depend on your own mass. It applies to everything from rockets to gas molecules.”

“And we were just talking about helium being zippy. Is it zippy enough to escape Earth?”

“Good thinking! That’s exactly where I was going. The answer is, ‘Maybe.’ It depends on temperature. Warm molecules are zippy, cold molecules not so much. At the same temperature, light molecules are zippier than heavy ones. There’s a chart that shows thresholds for different molecules escaping from different planets. Earth could hold onto its helium atoms, but only if our atmosphere were more than a hundred degrees colder than it is. Warm as we are, bye‑bye helium.”

“How long would that take?”

“That’s a complicated question with lots of ‘It depends’ in the answer. Probably the most important has to do with water.”

“I didn’t say anything about water, just helium and oxygen.”

“I know, but much of Earth’s weather is driven by water vaporizing or condensing or just carrying heat from place to place. Water‑powered hurricanes and even big thunderstorms stir up the atmosphere enough to swoosh helium up to bye‑bye territory. On the other hand, suppose our helium‑Earth is dry. The atmosphere’s layers would be mostly stable, light atoms would be slow to rise. We’d have a very odd‑looking sky.”

“No clouds.”

“Pretty much. But it wouldn’t be blue, either.”

“Would it be pink? I like pink.”

“Sorry, sweetie, it’d be dark dark blue, some lighter near the horizon. Light going past an atomic or molecular particle can scatter from its temporarily distorted electron cloud. Nitrogen and oxygen molecules distort more easily than helium atoms do. Earth skies are blue thanks to sunlight scattered by oxygen and nitrogen. Helium skies wouldn’t have much of that.”

~ Rich Olcott

  • Thanks again to Xander, who asked a really good helium question.

New Volcano, Old Crater

Now Eddie’s dealing the cards and the topic choice. “So I saw something on TV about a new volcano on Mars. You astronomy guys have been saying Mars is a dead planet, so what’s with a new volcano? Pot’s open.”

Vinnie’s got nothing, throws down his hand. So does Susan, but Kareem antes a few chips. “I doubt there’s a new volcano, it’s probably an old one that we just realized is there. We find a new old caldera on Earth almost every year. Sy, I’ll bet your tablet knows about it.”

I match Kareem’s bet and fire up Old Reliable. A quick search gets me to the news item. “You’re right, Kareem, it’s a new find of an old volcano. This article’s a puff‑piece but the subject’s in your bailiwick, Cathleen.”

Cathleen puts in her bet and pulls out her tablet. “You’re right, Kareem. It’s a volcano we all saw but no‑one recognized until this two‑person team did. Here’s a wide‑angle view of Mars to get you oriented. North is up top, east is to the right just like usual.”

“Gaah. Looks like a wound!”

“We’ll get to that. The colors code for elevation, purple for lowlands up through the rainbow to red, brown and white. Y’all know about Olympus Mons, the 22‑kilometer tallest volcano in the Solar System, and there’s Valles Marineris, at 4000 kilometers the longest canyon. The Tharsis bulge is red‑to‑pink because it’s higher than most all the rest of the planet’s surface. Do you see the hidden volcano?”

“It’s hard to tell the volcanos from the meteor craters.”

“Understandable. Let me switch to a closer view of the canyon’s western end. This one’s in visible light, no color‑coding games. The middle one of the three Tharsis volcanos is to the left, no ginormous meteor craters in the view. Noctis labyrinthus, ‘the Labyrinth of Night.’ is that badlands region left of center. Lots of crazy canyons that go helter‑skelter.”

“That’s more Mars‑ish, but it’s still unhealthy‑looking.”

“It is a bit rumpled. Do you see the volcano?”

“Mmm, no.”

“This should help. It’s a close-up using the elevation colors to improve contrast.”

“Wow, the area inside that circle sure does look like it’s organized around its center, not higgledy-piggledy like what’s west of it. That brown image had something peaky right about there. What’s ‘prov’?”

“Good eye, Susan. The ‘prov’ means ‘provisional‘ because names aren’t real until the International Astronomical Union blesses them. The peak is nine kilometers high, almost half the height of Olympus Mons. The concentric array of canyons and mesas around it certainly make it look like a collapsed and eroded volcano. But IAU demands more evidence than just ‘look like.’ Using detailed spectroscopic data from two different Mars orbiters, the team found evidence of hydrated minerals plus structural indications that their proposed volcano either punched through a glacier or flowed onto one. Better yet, the mesas all tilt away from the peak, and the minerals are what you’d expect from water reacting with fresh lava.”

“Did they use the word ‘ultramafic‘?”

“I don’t think so, Kareem, just ‘mafic‘.”

“From underground but not deep down, then.”

“I suppose.”

Cal bets. “You said we’d get back to wounds. What was that about?”

“Well, just look at all that mess related to the Tharsis bulge — higher than all its surroundings, massive volcanos nearby, the Noctis badlands, Valles Marineris that doesn’t look water‑carved but has that delta at its eastern end. Why is all of that clustered in just one part of the planet? Marsologists have dozens of hypotheses. My own favorite centers on Hellas basin. It’s the third largest meteor strike in the Solar System and just happens to be almost exactly on the opposite side of Mars.”

Eddie looks a bit gobsmacked. “A wallop like that would carry a lot of momentum. Kareem, can a planet’s interior just pass that along in a straight line?”

“Could be, depending. If it’s solid or high‑viscosity, I guess so. If it’s low‑viscosity you’d get a doughnut‑shaped circulatory pattern inside that’d turn the energy into heat and vulcanism. How long was Mars cooling before the hit?”

“We don’t know.”

Cal’s pair of jacks apologetically takes the pot.

~~ Rich Olcott

No Symphony on Mars

“Evening, Jeremy, a scoop of your pistachio gelato, please. What’re you reading there?”

“Hi, Mr Moire. It’s A City on Mars by Kelly and Zach Weinersmith. One of my girlfriends read it and passed it along to me. She said it’s been nominated for a Hugo even though it’s non‑fiction and it argues against the kind of go‑to‑Mars‑soon planning that Mr Musk is pushing.”

“Is she right about the argument?”

“Pretty much, so far, but I’m not quite done. You get a clue, though, from the book’s subtitle — ‘Can we settle space, should we settle space, and have we really thought this through?‘ Here’s your gelato.”

“Thanks. Not just Mars, space also?”

“That’s right. It’s about the requirements and implications for people living in space and on the Moon and on Mars. The discussion starts with making and raising babies.”

“That first part sounds like fun.”

“Well, you’d think so, but apparently you need special equipment. Hard to stay in contact if there’s no gravity to key on. But that’s only the start of a problem cascade. Suppose the lady gets pregnant. The good news is in zero gravity it’s easy for her to move around. The bad news is we don’t know whether Earth gravity’s important for making babies develop the way they’re supposed to. Also, delivering a baby isn’t the only medical procedure that’d be a real challenge in zero‑g where you need to keep fluid droplets from bouncing around the cabin and into the air system.”

“Whoa. Hmm, never thought about it in this context before, but babies leak. Diapers can help, but babies burp up stuff along with the air. Yuck! Tears they cry in space would just stay on their eyes instead of rolling down cheeks. So … we’d need OB/GYN clinics and nurseries somewhere down a gravity well.”

“For sure, although no‑one knows whether even the Moon’s 1/6g is strong enough for good development. I know my little cousins burn up a lot of energy just running around. Can’t give a toddler resistance bands or trust it on a treadmill.”

“So we need an all‑ages gym down there, too, with enough room for locals and visiting spacers.”

“You’re coming round to the Weinersmiths’ major recommendation — don’t go until you can go big! Don’t plan on growing from a small colony, plan on starting with a whole city that can support everything you need to be mostly self‑sufficient.”

“So you’re young, Jeremy. Are you looking forward to being a Mars explorer?”

“I’ll admit all that rusty landscape reminds me of Navajoland, but I think I’d rather stay here. On Mars I’d be trapped in tunnels and domes and respirators and protective coveralls. I wouldn’t be able to just go out and run under the sky the way I was brought up to do.”

“Wouldn’t be able to do a lot of things. Concerts would sound weird, according to a paper I just read.”

“Sure, wind instruments wouldn’t work with bubble helmets. We could still have strings, percussion and electronics, though, right?”

“Sure you could have them. But it’s worse than that. Mars atmosphere is very different from Earth’s. Its temperature measured in kelvins is 25% colder. The pressure’s 99% lower. Most important, molecule for molecule Mars’ mostly‑CO2 atmosphere’s is 50% heavier than Earth’s N2‑O2 mixture. Those differences combine to muffle sounds so they don’t carry near as far as they would on Earth. Most sounds travel about 30% more slowly, too, but that’s where a CO2 molecule’s internal operation makes things weird.”

“Internal? I thought molecules in sound waves just bounced off each other like little billiard balls.”

“That’s usually the case unless you’re at such high pressures that molecules can start sticking to each other. CO2 under Mars conditions is different. If there’s enough time between bounces, CO2 can convert some of its forward kinetic energy into random heat. The threshold is about 4 milliseconds. A sound wave frequency longer than that travels noticeably slower.”

“Four milliseconds is 250 Hertz — that’s a middle B.”

“Mm-hm. Hit a cymbal and base drum simultaneously, your audience hears the cymbal first. Terrible acoustics for a band.”

~~ Rich Olcott

A Spherical Bandstand

“Whoa, Sy, something’s not right. Your zonal harmonics — I can see how latitudes go from pole to pole and that’s all there are. Your sectorial harmonic longitudes start over when they get to 360°, fine. But this chart you showed us says that the radius basically disappears crazy close to zero. The radius should keep going forever, just like x, y and z do.”

“Ah, I see the confusion, Susan. The coordinate system and the harmonic systems and the waves are three different things, um, groups of things. You can think of a coordinate system as a multilevel stage where chords of harmonic musicians can interact to play a composition of wave signals. The spherical system has latitude and longitude levels for the brass and woodwind players, plus one in back for the linear percussion section. Whichever direction the brass and woodwinds point, that’s where the signals go out, but it’s the percussion that determines how far they get. Sure, radius lines extend to infinity but except for R0 radial harmonics damp out pretty quickly.”

“Signals… Like Kaski’s team interpreted Juno‘s orbital twitches as a signal about Jupiter’s gravitational unevenness. Good thing Juno got close enough to be inside the active range for those radial harmonics. How’d they figure that?”

“They probably didn’t, Cathleen, because radial harmonics don’t fit easily into real situations. First problem is scale — what units do you measure r in? There’s an easy answer if the system you’re working with is a solid ball, not so easy if it’s blurry like a protein blob or galaxy cluster.”

“What makes a ball easy?”

“Its rigid surface that doesn’t move so it’s always a node. Useful radial harmonics must have a node there, another node at zero and an integer number of nodes between. Better yet, with the ball’s radius as a natural length unit the r coordinate runs linearly between zero at the center and 1.0 at the surface. Simplifies computation and analysis. In contrast, blurries usually don’t have convenient natural radial units so we scrabble around for derived metrics like optical depth or mixing length. If we’re forced into doing that, though, we probably have worse challenges.”

“Like what?”

“Most real-world spherical systems aren’t the same all the way through. Jupiter, for instance, has separate layers of stratosphere, troposphere, several chemically distinct cloud‑phases, down to helium raining on layers of hydrogen in liquid, maybe slushy or even solid form. Each layer has its own suite of physical properties that put kinks into a radial harmonic’s smooth curve. Same problem with the Sun.”

“How about my atoms? The whole Periodic Table is based on atoms having a shell structure. What about the energy level diagrams for atomic spectra? They show shells.”

“Well, they do and they don’t, Susan. Around the turn of the last Century, Lyman, Balmer, Paschen, Brackett and Pfund—”

“Sounds like a law firm.”

“<ironically> Ha, ha. No, they were experimental physicists who gave the theoreticians an important puzzle. Over a 40‑year period first Balmer and then the others, one series at a time, measured the wavelengths of dozens of lines in hydrogen’s spectrum. ’Okay, smarties, explain those!‘ So the theoreticians invented quantum mechanics. The first shot did a pretty good job for hydrogen. It explained the lines as transitions between discrete states with different energy levels. It then explained the energy levels in terms of charge being concentrated at different distances from the nucleus. That’s where the shell idea came from. Unfortunately, the theory ran into problems for atoms with more than one electron.”

“Give us a second… Ah, I get why. If one electron avoids a node, another one dives in there and that radius isn’t a node any more.”

“Got it in one, Cathleen. Although I prefer to think of electrons as charge clouds rather than particles. Anyhow, when an atom has multiple charge concentrations their behavior is correlated. That opens the door to a flood of transitions between states that simply aren’t options for a single‑electron system. That’s why the visible spectrum of helium, with just one additional electron, has three times more lines than hydrogen does.”

“So do we walk away from spherical harmonics for atoms?”

“Oh, no, Susan, your familiar latitude and longitude harmonics fit well into the quantum framework. These days, though, we mostly use combinations of radial fade‑aways like my Sn00 example.”

~~ Rich Olcott

Jupiter And The Atoms

“Okay, Sy, what’s your third solution?”

“Solution to what, Susan?”

These harmonic thingies. They’re about angles so it makes sense to chart them in polar or spherical coordinates, but when they take on negative values the radius goes the wrong way. You said one solution was to chart the negatives in a different color. That’s confusing, though. Another solution is to square all the values to get everything into positive territory. That’s okay for chemists like me because the peaks and nodes we care about stay in the same places. What’s the third option?”

“One that gets to why these ‘harmonic thingies’ are interesting at all. When Juno‘s orbiting Jupiter, does it feel each of Kaspi’s Jn shapes individually?”

“No, of course not, she just reacts to how they all add togethherrr … Oh! So you’re saying we can handle negative values from one harmonic by adding it to another one that’s more positive and plotting the combination.”

<pointing to paper napkin> “Bingo! Remember this linear plot of J2 where I colored its negative section pink?” <pointing to display on Old Reliable> “When you multiply J2 by C0 you get S220. I added that to four helpings of Sn00 to get this combination.”

“Ah, that negative region in S220‘s middle shaves back the equator on Sn00‘s sphere while the positive part adds bumps top and bottom.” <Susan gives me the side‑eye> “Why’d you pick that 4‑to‑1 ratio, and what’s with those n subscripts instead of numbers?”

“Getting a little ahead of myself. For the moment let’s concentrate on Juno‘s experience with Jupiter’s gravity. One reason I chose that ratio was that it’s pretty easy to see in the picture. In real cases the physical system determines the ratios. Kaspi’s team derived their ratios experimentally. They used math to fit a model to Juno‘s very slightly wobbly orbit. Their model of Jupiter’s gravity field started from the spherical J0 shape. They tweaked that by adding different ratios of J2 through J40, adjusting the ratios until the model’s total gravity field predicted an orbit that matched the real‑world one. J2‘s share was about 15 parts per thousand but most of the rest contributed less than a part per million. Jupiter probably uses multiple mass blobs to make the J2 shape. The point is, the planet’s really a mess but we can analyze the mess in terms of the harmonics.”

“So that’s how you drew what Cal called your wiggle-waggles — you followed Kaski’s Jn recipe and then added some constant to push the polar plot out far enough that the negatives didn’t poke out the wrong side. That constant — what value did you use and why that one?”

“That’s exactly what I did do, Cathleen. Frankly, I don’t even remember what constant I added, just something that was big enough to make the negatives behave nicely, not so large that the peaks vanished by comparison. Calibrating accurately to Jupiter’s J0 would shrink the peaks down to parts‑per‑thousand invisibility. After all, I was more concerned with peak position than peak size.”

“Now we’re back to your 4‑to‑1 ratio. Was that arbitrary, too?”

“No, it wasn’t, Susan. Would it have been closer to Chemistry if I’d labeled that figure as 1s22s22p1?”

“Two electrons in the 1s‑shell, two in the 2s‑shell plus one 2p electron … that’s a boron atom? But you’re showing only one radial shell, not two separate ones.”

“True, but that’s to make another point. There isn’t an electron in the 1s shell, or even a pair of them nicely staying on opposite sides. The atom’s charge, all five electrons‑worth of it, is smeared out as a wave pattern across the entire structure. The Sn00 pattern captures everything that’s spherical. The S220 pattern gets what’s left.”

“But what about the radial nodes? Isn’t that the difference between 1s and 2s, that 2s has a node?”

“Oh there are nodes, alright, but they don’t have much effect. Each radial harmonic is the product of two factors — a polynomial and an exponential. The exponential part squeezes the polynomial so hard that adjacent peaks and valleys are barely bumps and dents.”

“So Jupiter and atoms use the same math, huh?”

“So does the Sun.”

~~ Rich Olcott

A Loose-end Lagniappe

<chirp, chirp> “Moire here.”

“We have some loose ends to tie up. Too early for pizza. Coffee at Cal’s?”

“Hello, ‘Walt‘. Fifteen minutes?”

“Confirmed.”


He’s at a back table, facing the door, of course. He points to the steaming mug and strawberry scone beside it on the table. I nod to acknowledge. ”So, Walt, what are these loose ends?”

“My people say that Juno‘s not on a 53‑day orbit any more. NASA’s jiggled it down to 33 days. What’s that do to the numbers you gave me?”

<sliding a folded paper scrap across the table> “I had a hunch you’d want more so I worked up estimates. Juno started with a 53‑day orbit but a Ganymede flyby dropped it to 43 days. A Europa flyby took Juno to a 38‑day orbit. Now it’s swerved by Io and we’re at 33 days. I threw in the 23‑day line for grins, no extra charge.”

“Half the orbit size but no significant change in the close‑in specs. That’s surprising.”

“Not really. It’s like a dog’s butt wagging its tail. At close approach, we call it perijove, Juno is only 76 500 kilometers out from Jupiter’s center. Its orbit thereabouts is pretty much nailed down by the big guy’s central field. But there’s no second attractor to constrain the orbit’s other extreme millions of kilometers out. Do an Oberth burn near perijove or arrange for a gravity tweak from a convenient moon, you get a big difference at the far end.”

“That wraps that.” <reaches for his cane, then settles back to do a Columbo> “Just one more thing, Moire. I came in with a question about the Sun’s effect on Juno. You took care of that pretty quick but spent a load of my time and consultancy budget on these spherical harmonics. How come?”

“As I recall, you and your people kept coming back for more detail. Also, the 225 000‑kilometer radius I got from R2‘s structure was essential in calculating these close‑in numbers. You’re getting your money’s worth. I’ll even throw in a lagniappe.”

“A free gift? I never trust them.”

“Such a mean world you live in, Walt.” <displaying an image on Old Reliable> “Here it is, take it or leave it.”

Top: F000 plus a time-varying contribution from F660
Bottom: C0 plus a time-varying contribution from C4

“What is it?”

“It’s a bridge between the physics of light and sound, and the physics of atoms and stars. When I say ‘coordinates,’ what words spring to your mind?”

“Traverse and elevation.”

“Interesting choice. Any other systems?”

“Mm, latitude, longitude and altitude. And x‑y‑z if you’re in a classroom.”

“Way beyond the classroom. You use spreadsheets, right?”

“Doesn’t everyone?”

“Rowscolumnssheets is xyz. On digital screens, pixelslinesluminosity is xyz. Descarte’s rectilinear invention is so deeply embedded in our thinking we don’t even notice it. Perpendicular straight‑line coordinates fit things that are flat or nearly so, not so good for spheres and central‑force problems. Movement there is mostly about rotation, which is why your first two picks were angular instead of linear.”

“Okay, but our choice of coordinates is our choice. What have xyz or your Fnnm to do with natural things?”

“Overtones and resonance. Look at that black line in the movie. It could be a guitar string or a violin string, doesn’t matter. One end’s fixed to the instrument’s bridge, the other end’s under somebody’s finger. All other points on the string are free to move, subject to tension along the string. Then someone adds energy to the string by plucking or bowing it.”

“At one of those peaks or valleys, right?”

“Nope, anywhere, which goes to my point. The energy potentially could contort the string to any shape. Doesn’t happen. The only stable shapes are combinations of sine waves with an integer number of nodes, like C4‘s quartet. Adding even more energy gives you overtones, waves that add in‑between nodes to lower‑energy waves. C0‘s no‑nodes black line could run along x, y or z in any flat system.”

“So you’re going to tell me that your C‘s, J‘s and R‘s support wave structures for spheres.”

“Indeed. All four giant planets have stripes along their J arcs. Solar seismologists have uncovered C, R and maybe J wave structures inside the Sun.”

“Bye.”

“Don’t mention it.”

~ Rich Olcott

Completing The Triad

Walt’s mustache bristles as he gives me the eye. ”You claim three harmonics control how the Sun’s gravity could affect spacecraft orbits around a target planet like Jupiter. You said we don’t have to care about Jupiter’s gravitational zones and isolating the sectors probably isn’t doable. What’s the third?”

Time to twist the screws. ”Three harmonic systems, Walt, all working together and you’ve got their names wrong. They control nothing, they’re a framework for analysis. And Jupiter’s special. Solar gravity doesn’t affect its zonal harmonic arcs but that’s only because Jupiter’s polar axis is nearly perpendicular to its orbital plane. Zonal‑effect N‑S twisting at Jupiter is pennies on a C‑note. Any mission we send to Mars, Saturn or Uranus we’ll care a lot about their zonal harmonics because their axes have more tilt. An 82° tilt for Uranus, can’t get much more tilted than that. Sectorial harmonics may still help us navigate there because Uranus probably has a lot less magnetism than Jupiter.”

That rocks him but he comes back strong. ”The third kind of harmonic?!! C’mon, give!”

“Radial, the center‑out dimension. The gravitational force between bodies depends on center‑to‑center distances so yeah, your people would be interested.”

“I presume radial harmonics have numbers like Jn and Cm do?”

“They do. Sorry, this’ll get technical again but I’ll go as light as I can. Each radial harmonic is the product of two factors. You know about factors, right?”

“Sure, force multipliers.”

“You would know that kind. More generally, factors are things that get multiplied together. I’ll call the general radial harmonic Rn. It’s the product of two factors. The first is a sum of terms that begin with rn, where r is the distance. For instance, R3‘s first factor would look like a*r³+b*r²+c*r+d, where the a,b,c,d are just some numbers. Different radial harmonics have different exponents in their lead terms. You still with me?”

“Polynomials from high school algebra. Tell me something new.”

“The second factor decreases exponentially with n*r. No matter how large rn gets, when you multiply an rn polynomial by something that decreases exponentially, the (polynomial)×(exponential) product eventually gets really small.”

“Give me a second. … So what you’re saying is, at a big enough distance these radial harmonics just die away.”

“That’s where I was going.”

“How far is ‘enough’?”

“Depends on n. Higher values of n shut down faster.”

“So these Cms and Jns and Rns just add together?” <pauses, squints at me suspiciously> “Is there some reason you used n for both Jn and Rn?”

“No but yes, and yes. You combine a C, a J and an R using multiplication to get a full harmonic F, except there are rules. The J and R must belong to the same n. The m can’t be larger than n. From far away we’d model Jupiter’s gravity as F000=R0×J0×C0, which is an infinite sphere — R0 never dies away and J0×C0 says ‘no angular dependence.’ The Sun’s gravity acts along R0 and that’s what keeps Jupiter in orbit. If the problem demands combining full harmonics, you use addition.” <rousing a display on Old Reliable> “Here’s how a particular pair of harmonics combine to increase or decrease spherical gravity in specific directions.”

“But Juno doesn’t see those gravity lumps until it gets close‑in. How close?”

R2‘s down to less than a part per thousand at three planetary radii, call it 225 000 kilometers away from the planet’s center.”

“How much time is it closer than that distance?”

“Complicated question. A precise answer requires some calculus — is your smart phone set up for elliptic integrals?”

“Of course not. A good estimate will do.”

“Okay, here’s the plan. What we’d like is total time spent while Juno travels along the ellipsoidal arc between points A and D where the orbit crosses the 225 000‑km circle. Unfortunately, Juno speeds up approaching point P, slows down going away — calculating the A‑D time is tricky. I’ll assume Juno travels straight lines AB and CD at the A-speed. I’ll also approximate the orbit’s close pass as a semicircle at P‑speed.” <tapping> “I get a 3.6-hour duration, less than 0.3% of the full 53-day orbit. Will that satisfy your people?”

“You’ll know if it doesn’t.”

~~ Rich Olcott