Category: Physics

The Latte Connection

On By rolcottIn Physics: Entropy and Thermodynamics, UncategorizedLeave a comment

An early taste of Spring’s in the air so Al’s set out tables in front of his coffee shop. I’m enjoying my usual black mud when the Chemistry Department’s Susan Kim passes by carrying her usual mocha latte. “Hi, Sy, mind if I take the socially distant chair at your table?”

“Be my guest, Susan. What’s going on in your world?”

“I’ve been enjoying your hysteresis series. It took me back to Physical Chemistry class. I’m intrigued by how you connected it to entropy.”

“How so?”

“I think of hysteresis as a process, but entropy is a fixed property of matter. If I’m holding twelve grams of carbon at room temperature, I know what its entropy is.”

“Mmm, sorta. Doesn’t it make a difference whether the carbon’s a 60‑carat diamond or just a pile of soot?”

“OK, I’ll give you that, the soot’s a lot more random than the diamond so its entropy is higher. The point remains, I could in principle measure a soot sample’s heat capacity at some convenient temperature and divide that by the temperature. I could repeat that at lower and lower temperatures down to near absolute zero. When I sum all those measurements I’ll have the entropy content of the sample at my starting temperature.”

“A classical definition, just what I’d expect from a chemist. But suppose your soot spills out of its test tube and the breeze spreads it all over the neighborhood. More randomness, higher entropy than what you measured, right?”

“Well, yes. I wouldn’t have a clue how to calculate it, but that goes way beyond Carnot’s and Clausius’ original concept.”

“So entropy has at least a thin linkage with history and hysteresis. To you chemists, though, an element or compound is timeless — lead or water have always been lead or water, and their physical constants are, well, constant.”

“Not quite true, Sy. Not with really big molecules like proteins and DNA and rubber and some plastics. Squirt a huge protein like catalase through a small orifice and its properties change drastically. It might not promote any reaction, much less the one Nature designed it for. Which makes me think — Chemistry is all about reactions and they take time and studying what makes reactions run fast or slow is a big part of the field. So we do pay attention to time.”

“Nice play, Susan! You’re saying small molecules aren’t complex enough to retain memories but big ones are. I’ll bet big molecules probably exhibit hysteresis.”

“Sure they do. Rubber molecules are long-chain polymers. Quickly stretch a rubber band to its limit, hold it there a few seconds then let go. Some of the molecular strands lock into the stretched configuration so the band won’t immediately shrink all the way down to its original size. There’s your molecular memory.”

“And a good example it is — classic linear Physics. How much force you exert, times the distance you applied it through, equals the energy you expended. Energy’s stored in the rubber’s elasticity when you stretch it, and the energy comes back out on release.”

“Mostly right, Sy. You actually have to put in more energy than you get out — Second Law of Thermodynamics, of course — and the relationship’s not linear. <rummaging into purse> Thought I had a good fat rubber band somewhere … ah‑hah! Here, stretch this out while you hold it against your forehead. Feel it heat up briefly? Now keep checking for heat while you relax the band.”

“Hey, it got cold for a second!”

“Yep. The stretched-out configuration is less random so its entropy and heat capacity are lower than the relaxed configuration’s. The stretched band had the same amount of heat energy but with less heat required per degree of temperature, that amount of energy made the band hotter. Relaxing the band let its molecules get less orderly. Heat capacity went back up. temperature went back down.”

“Mmm-HM. My hysteresis diagram’s upward branch is stretch energy input and the downward branch is elastic energy output. The energy difference is the area inside the hysteresis curve, which is what’s lost to entropy in each cycle and there we have your intriguing entropy‑hysteresis connection. Still intrigued?”

“Enough for another latte.”

~~ Rich Olcott

Hysteresis Everywhere

On By rolcottIn Physics: Gaps, Physics: Money, UncategorizedLeave a comment

“We’ve known each other for a long time, ain’t we, Sy?”

“That we have, Vinnie.”

“So I get suspicious when we’ve specific been talking about a magnetic field making something else magnetic and you keep using general words like ‘driver‘ and ‘deviation‘. You playing games?”

“You caught me. The hysteresis idea spreads a lot farther than magnetism. It addresses an entire dimension Newton was too busy to think about — time.”

“Wait a minute. Newton was all about velocity and acceleration and both of them are something‑per‑time. It’s right there in the units. Twice for acceleration.”

“True, but each is really about brief time intervals. Say you’re riding a roller‑coaster. Your velocity and acceleration change second‑by‑second as forces come at you. Every force changes your net acceleration immediately, not ten minutes from now. Hysteresis is about change that happens because of a cause some time in the past. Newton didn’t tackle time‑offset problems, I suppose mostly because the effects weren’t detectable with the technology of his time.”

“They had magnets.”

“Permanent ones, not electromagnets they could control and measure the effects of. Electromagnetic hysteresis generates effects that Newton couldn’t have known about. Fahrenheit didn’t invent temperature measurement until two years before Newton died, so science hadn’t yet discovered temperature‑dependent hysteresis effects. The microscope had been around for a half‑century or so but in Newton’s day people were still arguing about whether cells were a necessary part of a living organism. Newton’s world didn’t have an inkling of cellular biophysics, much less biophysical hysteresis. At human scale, country‑level economic data if it existed at all was a military secret — not a good environment for studying cases of economic hysteresis.”

“So what you’re saying is that Newton couldn’t have tackled those even if he’d wanted to. Got it. But that’s a pretty broad list of situations. How can you say they’re all hystereseseses, … loopy things?”

“They’ve all got a set of characteristics that you can fit into similar mathematical models. They’re all about some statistical summary of a complex system. The system is under the influence of some outside driver, could be a physical force or something more abstract. The driver can work in either of two opposing directions, and the system can respond to the driver to change in either of two opposing ways. Oh, and a crucial characteristic is that the system has a buffer of some sort that saves a memory of what the driver did and serves it up some time later.”

“Wait, lemme see if I can match those pieces to my magnetic nail. OK, the driver is the outside magnetic field, that’s easy, the system is the magnetic iron atoms, and the summary is the nail’s field. The driver can point north‑to‑south or south‑to‑north and the atoms can, too. Ah, and the memory is the domains ’cause the big ones hold onto the direction the field pointed last. How’d I do?”

“Perfect.”

“Goody for me. So why are those guys on the radio saying the economy is hysterical, ‘scuse, has hysteresis? What’s which part?”

“Economies are complex beasts, with a lot of separate but interacting hysteresis loops. These guys, what were they discussing at the time?”

“Unemployment, if I remember right. They said the job market is sticky, whatever that means.”

“Good example. Here’s our basic hysteresis loop with some relabeling. Running across we’ve got our driver, the velocity of money, which claims to measure all the buying and selling. Up‑and‑down we’ve got total employment. The red dot is the initial equilibrium, some intermediate level where there’s just enough cash flowing around that some but not all people have jobs. Then a new industry, say cellphones, comes in. Suddenly there’s people making cellphones, selling cellphones, repairing cellphones –“

“I get the idea. More activity, money flows faster, more jobs and people are happy. OK, then the pandemic comes along, money slows down, jobs cut back and around we go. But where’s the stickiness?”

“In people’s heads. If they get into Depression thinking, everyone holds onto cash even if there’s a wonderful new cellphone out there. People have to start thinking that conditions will improve before conditions can improve. That’s the delay factor.”

“Hysterical, all right.”

~~ Rich Olcott

Elephant And Pengy

On By rolcottIn Physics: Entropy and Thermodynamics, Physics: GapsLeave a comment

(a hat-tip to Mo Willems, whose Elephant and Piggy books helped my grandkids discover reading)

“Hey, Sy, how come my magnetized nail’s hysteresis loop is so wide? It makes sense that the end‑case magnetizing happens because all the iron atoms get lined up in one direction or the other. But why ain’t the blue up‑curve right on top of the down‑curve?”

“Why do you think it should be, Vinnie?”

“Well, the red curve’s different because you got the outside field herding the iron atoms into domains where they all point the same way and that makes the nail’s magnetism grow from zero, and then the domains that agree with the outside magnetic field eat up the other domains until like I said they saturate. But on both sides of the blue loop the domains already exist, right, so the herding’s all done. Up or down it’s only domains growing and shrinking. Seems to me that the curves oughta be the same.”

“They are, near as I could draw them. You’re just not looking at them right. Rotate it 180°, see how they match up.”

“How ’bout that, they do, mostly. What’s going on?”

“You picked up that the vertical axis represents strength and direction, but you missed that the horizontal axis also represents strength and direction. Neither axis starts at zero, they’re both centered on zero. The driver is the outside magnetic field. No strength in the middle, increasing north‑bound strength to the right, south‑bound strength to the left. Start at the head‑end‑north corner and go down branch 2. The north‑bound driver strength decreases. That relaxes some of those north‑pointing domains and the nail’s net magnetism decreases just a bit. When the outside field’s strength gets down to neutral, about at the upper arrow, the nail’s still strongly magnetized. Most of the domains remember which way they were pointing. That’s the history that makes this hysteresis. The domains stay there until the outside field gets strong enough south‑bound to make a difference. That grows the south‑bound domains at the expense of northbound ones. All that goes on until we get to saturation at head‑end‑south corner and then we run exactly the reverse sequence. For most materials, the two extreme fields have the same strength, just opposite directions.”

“Wait, you said ‘for most materials.’ Different materials have different widths on that picture?”

“Good catch. Yes, there’s ‘hard‘ ones like rare earth magnets. They have a really wide hysteresis loop you can’t demagnetize without a really strong field. That’s good for where you want a permanent magnet that you don’t want to have to recalibrate, like on a spacecraft bound for Jupiter. You’d want a ‘soft magnet‘ with a narrow hysteresis loop for something like a transformer core that has to switch polarity sixty times a second.”

<longish contemplative silence> “Sy, I just got a great idea! And it uses that entropy elephant stuff you wrote about.”

“All right, out with it.”

“OK. When the nail is magnetized, it’s got all or at least most of its iron atoms pointing in the same direction, right? And when the outside field demagnetizes it, the atoms point all over the place, right? So the not‑magnetized nail has randomness, that’s entropy, and the magnetized one doesn’t. Where did the entropy come from? Gotta be from the outside, right? Can we use this to like suck entropy out of things?”

“Right, right and sorta right. I’m not happy with the idea of pumping entropy around. What’s really in play is energy, sometimes as magnetic field energy and sometimes as heat. You’ve got the core idea for a magnetic refrigerator. Put a field‑magnetized transfer material in contact with what you want to cool, then turn off the outside field. Heat from the target flows into the material, jiggles the atoms and scrambles the magnetization. Break the contact, cool and re‑magnetize the material and repeat. The idea’s been around since the late 1800s. The problem has been finding the right material to make it work. The best stuff has a tall, narrow hysteresis loop so it can be strongly magnetized yet forget it easily. Researchers have finally found some good candidates.”

“Too late to the party, huh?”

“Sorry.”

~~ Rich Olcott

The Tale of A Nail

On By rolcottIn Physics: Electromagnetism, Physics: Gaps, UncategorizedLeave a comment

“Wait, Sy, let me get my head around that hysteresis loop diagram. You got my iron nail starting at that red dot because it’s not magnetized yet so that’s zero on the up‑down magnetism deviation scale, right? And it’s also zero on the left‑right driver scale because we’re not laying a magnetic field on it.”

“Yup, that’s the starting point, Vinnie.”

“OK, then we turn on the outside field and if it’s strong enough the nail gets magnetic, too, and so we travel up the red line. But the line’s not straight, it’s bendy. Why ain’t it straight?”

“To keep this specific, I’ll stick to the current theory for magnetization of iron. At point zero the individual iron atoms have their personal magnetic fields in completely random orientations. What we measure outside the nail is the average of all of that, which nets out to zero. Now we turn on the external magnetic field a little bit at a time so we can measure the effect. You remember we said that the iron atoms in a magnet are organized in domains.”

“Sure. I don’t forget easy.”

“I’ve noticed. OK, that upward bend at the beginning is slow increase in the nail’s magnetization while those domains are forming up. First a few atoms in one small area orient their local fields relative to the external field. Their combined field influences neighboring atoms to join in. The process is called nucleation because those first few atoms form the nucleus of a domain. The nucleus gains strength by recruiting more atoms, making it an even stronger recruiter. The red line rises exponentially until there aren’t any more unrecruited atoms.”

“That’s the end of the upward bend, huh?”

“Mm-hm, now we enter the linear phase and a different magnetization process. Energy in the external field feeds the domains pointed parallel to it at the expense of domains at a different angle. Domain growth is roughly linear with applied field strength. That line would like to stay straight but nothing goes on forever except maybe the Universe. Sooner or later the domains start running out of room to grow into. Increasing the driver strength doesn’t produce any further effect and we say that the nail’s magnetic field is saturated.”

“That makes sense. Let’s see if I can figure the blue loop from where the head end is north. The number 2 arrow says that if we dial down the driver, that’s the outside field and we’re moving to the left, when we get to zero the deviation, that’s the nail’s field, is still going strong and we got a permanent magnet. If we adjust the outside field leftward beyond zero that kills off the nail’s field … Hey, so the backward domains are eating the forward ones, right?”

“Probably. Depends on the material. Not good to ride the theory too far without checking the experimental data but that’d be my guess.”

“OK, so we drive those little domains until they saturate with the head end south. When we dial down the driver’s field backward strength we move to the right and the nail climbs the number 3 curve. The driver field returns to zero but the nail’s still a backward permanent magnet. We push the driver and the nail to forward saturation again and we can go loop‑de‑loop. But we never go through the red dot again — either the nail’s a permanent magnet when the driver’s zero or it not a magnet while the driver’s strong but they’re never both zero again.”

“Unless we scramble all the domains by heating the nail white-hot and letting it cool away from any external fields.”

“You know what’s missing from that picture, Sy?”

I’d wondered if he’d spot it. “I’ll bite. What?”

“Numbers. Up‑down is how strong the magnet is, right, but I know my knife‑holder magnets are a lot stronger than my calendar marker magnets. And the side‑to‑side part is about how well the stuff holds its magnetism. What’s the theory that puts numbers on the graph?”

“Sorry to tell you this given your math aversion, Vinnie, but the numbers are buried in big, thick books with equations in them. Pictures can only get you so far.”

~~ Rich Olcott

The Hysterical Penguin

On By rolcottIn Mathematics, Physics: Gaps, Physics: Newton and Gravity, UncategorizedLeave a comment

“Sy, you said that hysteresis researchers filled in two of Newton’s Physics gaps. OK, I get that he couldn’t do atomic stuff ’cause atoms hadn’t been discovered yet. What’s the other one?”

Proposition XI, Problem VI
from Book I of Newton’s Principia

“Non‑linearity.”

“You’re gonna have to explain that.”

“It’s a math thing. I know you don’t go for equations, so here’s a picture to get you started on how Newton solved problems. Look at all familiar?”

“Whoa, looks like something toward the end of my Geometry class.”

“Exactly. Newton was trained as a geometer and he was good at it. His general strategy was to translate a physical system to a geometrical structure and then work out its properties as a series of geometric proofs. The good news was that he proved a lot of things that started us on the way to quantitative science. The bad news was that his proofs were hard to extend to situations where the geometry wasn’t so easy.”

“That’s easy?”

“For Newton, maybe it was. Who knows? Anyway, the toolkit they gave you in Geometry class was what Newton had to work with — logic, straight lines and some special curves like ellipses and parabolas whose properties had been studied since Euclid, all on a flat plane. Nearly everything depended on finding proportionalities between different distances or areas — this line is twice that one but equal to a third, that sort of thing. Proportionality like that is built into equations like here+(velocity×time)=there. See how distance traveled is proportional to time? The equation plots as a straight line, which is why it’s called a linear equation.”

“So what’s non‑linear look like — all wiggle‑waggle?”

“Not necessarily. Things can vary smoothly along curves that aren’t those classical ones. Newton’s methods are blocked on those but Leibniz’s algebra‑based calculus isn’t. That’s why it won out with people who needed answers. What’s important here is that Newton’s lines can’t describe everything. Mmm… where does a straight line end?”

“Either at a T or never. Same thing for a parabola. Hey, ellipses don’t really end, either.”

“Mm-hm. Newton’s lines either stop abruptly or they continue forever. They don’t grow or peter out exponentially like things in real life do. Suppose something’s velocity changes, for instance.”

“That’s acceleration. I like accelerating.”

“So true, I’ve experienced your driving. But even you don’t accelerate at a constant rate. You go heavy or light or maybe brake, whatever, and our speed goes up or down depending. The only way Newton’s geometry can handle variable acceleration is to break it into mostly‑constant pieces and work one piece at a time. Come to think of it, that may be where he got the idea for his fluxions method for calculus. Fortunately for him, some things like planets and artillery shells move pretty close to what his methods predict. Unfortunately, things like disease epidemics and economies don’t, which is why people are interested in non‑linearity.”

“So what do these hysteresis guys do about it?”

“Mostly algebraic calculus or computer approximations. But there wasn’t just one group of hysteresis guys, there was a bunch of groups, each looking at different phenomena where history makes a difference. Each group had their own method of attack.”

“Like your elephant thing with Anne, lots of notions about entropy.”

Typical hysteresis loop
Red — initial evolution
Blue — subsequent changes

“How’d you find out about that?”

“You wrote those posts, Sy, about three years ago.”

“Oh, that’s right. Talk about history. Anyway, it took decades for the ecologists, epidemiologists, civil engineers and several kinds of physicist to realize that they all have systems that behave similarly when driven by a stressor. Starting at some neutral situation, the system evolves in the driver’s direction to some maximum deviation where increased stress has no further effect. When the stress is relieved, the system may stick temporarily at the strained position. When it does evolve away from there, maybe a reverse driver is needed to force a return to the starting situation. In fact, if the forward and reverse drivers are applied repeatedly the system may never get back to the initial unstressed position.”

“Like that iron nail. Not magnetic, then magnetic, then reversed.”

~~ Rich Olcott

Hysteria

On By rolcottIn Physics: Gaps, Physics: Money, UncategorizedLeave a comment

<chirp, chirp> “Moire here.”

“Hi, Sy, it’s Vinnie again. Hey, I just heard something on NPR I wanted to check with you on.”

“What’s that?”

“They said that even with the vaccine and all, it’s gonna take years for us to get back to normal ’cause the economy’s hysterical. Does that mean it’s cryin’‑funny or just cryin’? Neither one seems to fit.”

“You’re right about the no‑fit. Hmm… Ah! Could the word have been ‘hysteresis‘?”

“Somethin’ like that. What’s it about?”

“It’s an old Physics word that’s been picked up by other fields. Not misused as badly as ‘quantum,’ thank goodness, but still. The word itself gives you a clue. Do you hear the ‘history‘ in there?”

“Hysteresis, history … cute. So it’s about history?”

“Yup. The classic case is magnetism. Take an iron nail, for instance. The nail might already be magnetized strongly enough to pick up a paper clip. If it can, you can erase the magnetism by heating the nail white‑hot. If the nail’s not magnetic you may be able to magnetize it by giving it a few hammer‑whacks while it’s pointed north‑south, parallel to Earth’s magnetic field. Things get more interesting if we get quantitative. A strong‑enough magnetic field will induce magnetism in that nail no matter what direction it’s pointed. Reverse that field’s direction and the nail stays magnetized, only less so. It takes a stronger reverse field to demagnetize the nail than it took to magnetize it in the first place. See how the history makes a difference?”

“Yeah, for some things.”

“And that’s the point. Some of a system’s properties are as fixed as the nail’s weight or chemical composition. However, it may have other properties we can’t understand without knowing the history. Usually we can’t even predict them without looking at deeper structures. Hysteresis highlights two more gaps in Newton’s Physics. As usual he’s got a good excuse because many history‑dependent phenomena couldn’t even be detected with 17th‑Century technology. We couldn’t produce controllable magnetic fields until the 19th Century, when Oersted and Ampere studied magnetism and electricity. We didn’t understand magnetic hysteresis until the 20th Century.”

“Haw! You’re talking history of history. Anyway, to me it looks like what’s going on is that the strong field gets the magnetic atoms in there to all point the same way and heat undoes that by shaking them up to point random‑like.”

“What about the reversing field?”

“Maybe it points some of the atoms in the other direction and that makes the nail less and less magnetic until the field is strong enough to point everything backwards.”

“Close enough. The real story is that the atoms, iron in this case, are organized in groups called domains. The direction‑switching happens at the domain level — battalions of magnetically aligned atoms — but we had no way to know that until 20th‑Century microscopy came along.”

“So it takes ’em a while to get rearranged, huh?”

“Mmm, that’d be rate-dependent hysteresis, where the difference between forward and backward virtually disappears if you go slow enough. Think about putting your hand slowly into a tub of water versus splashing in there. Slow in, slow out reverses pretty well, but if you splash the water’s in turmoil for quite a long time. Magnetic hysteresis, though, doesn’t care about speed except in the extreme case. It’s purely controlled by the strength of the applied field.”

“I’m thinking about that poor frog.”

‘You would go there, wouldn’t you? Yeah, the legendary frog in slowly heating water would be another history dependency but it’s a different kind. The nail’s magnetism only depends on atoms standing in alignment. A frog is a highly organized system, lots of subsystems that all have to work together. Warming water adds energy that will speed up some subsystems more than others. If Froggy exits the pot before things desynchronize too far then it can recover its original lively state. If it’s trapped in there you’ve got frog soup. By the way, it’s a myth that the frog won’t try to hop out if you warm the water slowly. Frogs move to someplace cool if they get hotter than their personal threshold temperature.”

“Frogs are smarter than legends, huh?”

~~ Rich Olcott

‘Twixt A Rock And A Vortex

On By rolcottIn Physics: Gaps, Physics: Light and Relativity, Physics: Newton and Gravity, UncategorizedLeave a comment

A chilly late December walk in the park and there’s Vinnie on a lakeside bench, staring at the geese and looking morose. “Hi, Vinnie, why so down on such a bright day?”

“Hi, Sy. I guess you ain’t heard. Frankie’s got the ‘rona.”

“Frankie??!? The guys got the constitution of an ox. I don’t think he’s ever been sick in his life.”

“Probably not. Remember when that bug going around last January had everyone coughing for a week? Passed him right by. This time’s different. Three days after he showed a fever, bang, he’s in the hospital.”

“Wow. How’s Emma?”

“She had it first — a week of headaches and coughing. She’s OK now but worried sick. Hospital won’t let her in to see him, of course, which is a good thing I suppose so she can stay home with the kids and their schoolwork.”

“Bummer. We knew it was coming but…”

“Yeah. Makes a difference when it’s someone you know. Hey, do me a favor — throw some science at me, get my mind off this for a while.”

“That’s a big assignment, considering. Let’s see … patient, pandemic … Ah! E pluribus unum and back again.”

“Come again?”

“One of the gaps that stand between Physics and being an exact science.”

“I thought Physics was exact.”

“Good to fifteen decimal places in a few special experiments, but hardly exact. There’s many a slip ‘twixt theory and practice. One of the slips is the gap between kinematic physics, about how separate objects interact, and continuum physics, where you’re looking at one big thing.”

“This is sounding like that Loschmidt guy again.”

“It’s related but bigger. Newton worked on both sides of this one. On the kinematics side there’s billiard balls and planets and such. Assuming no frictional energy loss, Newton’s Three Laws and his Law of Gravity let us calculate exact predictions for their future trajectories … unless you’ve got more than three objects in play. It’s mathematically impossible to write exact predictions for four or more objects unless they start in one of a few special configurations. Newton didn’t do atoms, no surprise, but his work led to Schrödinger’s equation for an exact description of single electron, single nucleus systems. Anything more complicated, all we can do is approximate.”

“Computers. They do a lot with computers.”

“True, but that’s still approximating. Time‑step by time‑step and you never know what might sneak in or out between steps.”

“What’s ‘continuum‘ about then? Q on Star trek?”

“Hardly, we’re talking predictability here. Q’s thing is unpredictability. A physics continuum is a solid or fluid with no relevant internal structure, just an unbroken mass from one edge to the other. Newton showed how to analyze a continuum’s smooth churning by considering the forces that act on an imaginary isolated packet of stuff at various points in there. He basically invented the idea of viscosity as a way to account for friction between a fluid and the walls of the pipe it’s flowing through.”

“Smooth churning, eh? I see a problem.”

“What’s that?”

“The eddies and whirlpools I see when I row — not smooth.”

“Good point. In fact, that’s the point I was getting to. We can use extensions of Newton’s technique to handle a single well‑behaved whirlpool, but in real life big whirlpools throw off smaller ones and they spawn eddies and mini‑vortices and so on, all the way down to atom level. That turns out to be another intractable calculation, just as impossible as the many‑body particle mechanics problem.”

“Ah‑hah! That’s the gap! Newton just did the simple stuff at both ends, stayed away from the middle where things get complicated.”

“Exactly. To his credit, though, he pointed the way for the rest of us.”

“So how can you handle the middle?”

“The same thing that quantum mechanics does — use statistics. That’s if the math expressions are average‑able which sometimes they’re not, and if statistical numbers are good enough for why you’re doing the calculation. Not good enough for weather prediction, for instance — climate is about averages but weather needs specifics.”

“Yeah, like it’s just started to snow which I wasn’t expecting. I’m heading home. See ya, Sy.”

“See ya, Vinnie. … Frankie. … Geez.“

~~ Rich Olcott

Futile? Nope, Just Zero

On By rolcottIn Physics: Electromagnetism, UncategorizedLeave a comment

“Megabar superconductivity.”

“Whoa, Susan. Too much information, too few words. Could you unpack that, please?”

“No problem, Sy. A bar is the barometric pressure (get it?) at sea level. A megabar is—”

“A million atmospheres, right?”

“Right, Al. So Ranga Dias and his crew were using their Diamond Anvil Cells to put their chemical samples under million-atmosphere pressures while they tested for superconductivity—”

“Like Superman uses?”

“Is he always like this, Sy?”

“Just when he gets excited, Susan. The guy loves Science, what can I say?”

“Sorry, Susan. So what makes conductivity into superconductivity?”

“Excellent question, Al. Answering it generated several Nobel Prizes and we still don’t have a complete explanation. I can tell you the what but I can’t give you a firm why. Mmm… what do you know about electrical resistance?”

“Just what we got in High School General Science. We built a circuit with a battery and a switch and an unknown resistor and a meter to measure the current. We figured the resistance from the voltage divided by the current. Or maybe the other way around.”

“You got it right the first try. The voltage drop across a resistor is the current times the resistance, V=IR so V/I=R. That’s for ordinary materials under ordinary conditions. But early last century researchers found that for many materials, if you get them cold enough the resistance is zero.”

“Zero? But … if you put any voltage across something like that it could swallow an infinite amount of current.”

“Whoa, Al, what’s my motto about infinities?”

“Oh yeah, Sy. ‘If your theory contains an infinity, you’ve left out physics that would stop that.’ So what’d stop an infinite current here?”

“The resistor wasn’t the only element in your experimental circuit. Internal resistance within the battery and meter would limit the current. Those 20th-century researchers had to use some clever techniques to measure what they had. Back to you, Susan.”

“Thanks, Sy. I’m going to remember that motto. Bottom line, Al, superconductors have zero resistance but only under the right conditions. You start with your test material, with a reasonable resistance at some reasonable temperature, and then keep measuring its resistance as you slowly chill it. If it’s willing to superconduct, at some critical temperature you see the resistance abruptly drop straight down to zero. The critical temperature varies with different materials. The weird thing is, once the materials are below their personal critical temperature all superconductors behave the same way. It’s seems to be all about the electrons and they don’t care what kind of atom they rode in on.”

“Wouldn’t copper superconduct better than iron?”

“Oddly enough, pure copper doesn’t superconduct at all. Iron and lead both superconduct and so do some weird copper-containing oxides. Oh, and superconductivity has another funny dependency — it’s blocked by strong magnetic fields, but on the other hand it blocks out weaker ones. Under normal conditions, a magnetic field can penetrate deep into most materials. However, a superconducting piece of material completely repels the field, forces the magnetic lines to go around it. That’s called the Meissner effect and it’s quantum and—”

“How’s it work?”

“Even though we’ve got a good theory for the materials with low critical temperature, the copper oxides and such are still a puzzle. Here’s a diagram I built for one of my classes…”

“The top half is the ordinary situation, like in a copper wire. Most of the current is carried by electrons near the surface, but there’s a lot of random motion there, electrons bouncing off of impurities and crystal defects and boundaries. That’s where ordinary conduction’s resistance comes from. Compare that with the diagram’s bottom half, a seriously simplified view of superconduction. Here the electrons act like soldiers on parade, all quantum‑entangled with each other and moving as one big unit.”

“The green spirals?”

“They represent an imposed magnetic field. See the red bits diving into the ordinary conductor? But the superconducting parade doesn’t make space for the circular motion that magnetism tries to impose. The force lines just bounce off. Fun fact — the supercurrent itself generates a huge magnetic field but only outside the superconductor.”

“How ’bout that? So how is megabar superconductivity different?”

~~ Rich Olcott

A Star’s Tale

On By rolcottIn Astronomy: Stellar Science, Physics: Black Holes and Relativity, UncategorizedLeave a comment

It’s getting nippy outside so Al’s moved his out‑front coffee cart into his shop. Jeremy’s manning the curbside take‑out window but I’m walking so I step inside. Limited seating, of course. “Morning, Al. Here’s my hiking mug, fill ‘er up with high‑test and I’ll take a couple of those scones — one orange, one blueberry. Good news that the Governor let you open up.”

“You know it, Sy. Me and my suppliers have been on the phone every day. Good thing we’ve got long‑term relationships and they’ve been willing to carry me but it gets on my conscience ’cause they’re in a crack, too, ya know?”

“Low velocity of money hurts everybody, Al. Those DC doofuses and their political kabuki … but don’t get me started. Hey, you’ve got a new poster over the cash register.”

“You noticed. Yeah, it’s a beaut. Some artist’s idea of what it’d look like when a star gets spaghettified and eaten by a black hole. See, it’s got jets and a dust dusk and everything.”

“Very nice, except for a few small problems. That’s not spaghettification, the scale is all wrong and that tail-looking thing … no.”

Artist’s impression of AT2019qiz. Credit: ESO/M. Kornmesser
Under Creative Commons Attribution 4.0 International License

“Not spaghettification? That’s what was in the headline.”

“Sloppy word choice. True spaghettification acts on solid objects. Gravity’s force increases rapidly as you approach the gravitational center. Suppose you’re in a kilometer-long star cruiser that’s pointing toward a black hole from three kilometers away. The cruiser’s tail is four kilometers out. Newton’s Law of Gravity says the black hole pulls almost twice as hard on the nose as on the tail. If the overall field is strong enough it’d stretch the cruiser like taffy. Larry Niven wrote about the effect in his short story, Neutron Star.”

“The black hole’s stretching the star, right?”

“Nup, because a star isn’t solid. It’s fluid, basically a gas held together by its own gravity. You can’t pull on a piece of gas to stretch the whole mass. Your news story should have said ‘tidal disruption event‘ but I guess that wouldn’t have fit the headline space. Anyhow, an atom in the star’s atmosphere is subject to three forces — thermal expansion away from any gravitational center, gravitational attraction toward its home star and gravitational attraction toward the black hole. The star breaks up atom by atom when the two bodies get close enough that the black hole’s attraction matches the star’s surface gravity. That’s where the scale problem comes in.”

Al looks around — no waiting customers so he strings me along. “How?”

“The supermassive black hole in the picture, AT2019qiz, masses about a million Suns‑worth. The Sun‑size star can barely hold onto a gas atom at one star‑radius from the star’s center. The black hole can grab that atom from a thousand star‑radii away, about where Saturn is in our Solar System. The artist apparently imagined himself to be past the star and about where Earth is to the Sun, 100 star‑radii further out. Perspective will make the black hole pretty small.”

“But that’s a HUGE black hole!”

“True, mass‑wise, not so much diameter‑wise. Our Sun’s about 864,000 miles wide. If it were to just collapse to a black hole, which it couldn’t, its Event Horizon would be about 4 miles wide. The Event Horizon of a black hole a million times as massive as the Sun would be less than 5 times as wide as the Sun. Throw in the perspective factor and that black circle should be less than half as wide as the star’s circle.”

“What about the comet‑tail?”

“The picture makes you think of a comet escaping outward but really the star’s material is headed inward and it wouldn’t be that pretty. The disruption process is chaotic and exponential. The star’s gravity weakens as it loses mass but the loss is lop‑sided. Down at the star’s core where the nuclear reactions happen the steady burn becomes an irregular pulse. The tail should flare out near the star. The rest should be jagged and lumpy.”

“And when enough gets ripped away…”

“BLOOEY!”

~~ Rich Olcott

  • Thanks to T K Anderson for suggesting this topic.
  • Link to Technical PS — Where Do Those Numbers Come From?.

A Beetled Brow

On By rolcottIn Physics: Entropy and Thermodynamics, Physics: Gaps, UncategorizedLeave a comment

Vinnie’s brow was wrinkling so hard I could hear it over the phone. “Boltzmann, Boltzmann, where’d I hear that name before? … Got it! That’s one of those constants, ain’t it, Sy? Molecules or temperature or something?”

“The second one, Vinnie. Avagadro was the molecule counter. Good memory. Come to think of it, both Boltzmann and Avagadro bridged gaps that Loschmidt worked on.”

“Loschmidt’s thing was the paradox, right, between Newton saying events can back up and thermodynamics saying no, they can’t. You said Boltzmann’s Statistical Mechanics solved that, but I’m still not clear how.”

“Let me think of an example. … Ah, you’ve got those rose bushes in front of your place. I’ll bet you’ve also put up a Japanese beetle trap to protect them.”

“Absolutely. Those bugs would demolish my flowers. The trap’s lure draws them away to my back yard. Most of them stay there ’cause they fall into the trap’s bag and can’t get out.”

“Glad it works so well for you. OK, Newton would look at individual beetles. He’d see right off that they fly mostly in straight lines. He’d measure the force of the wind and write down an equation for how the wind affects a beetle’s flight path. If the wind suddenly blew in the opposite direction, that’d be like the clock running backwards. His same equation would predict the beetle’s new flight path under the changed conditions. You with me?”

“Yeah, no problem.”

“Boltzmann would look at the whole swarm. He’d start by evaluating the average point‑to‑point beetle flight, which he’d call ‘mean free path.’ He’d probably focus on the flight speed and in‑the‑air time fraction. With those, if you tell him how many beetles you’ve got he could generate predictions like inter‑beetle separation and how long it’d take an incoming batch of beetles to cross your yard. However, predicting where a specific beetle will land next? Can’t do that.”

“Who cares about one beetle?”

“Well, another beetle might. …
Just thought of a way that Statistical Mechanics could actually be useful in this application. Once Boltzmann has his numbers for an untreated area, you could put in a series of checkpoints with different lures. Then he could develop efficiency parameters just by watching the beetle flying patterns. No need to empty traps. Anyhow, you get the idea.”

Japanese Beetle, photo by David Cappaert, Bugwood.org
under Creative Commons BY 3.0

“Hey, I feel good emptying that trap, I’m like standing up for my roses. Anyway, so how does Avagadro play into this?”

“Indirectly and he was half a century earlier. In 1805 Gay‑Lussac showed that if you keep the pressure and temperature constant, it tales two volumes of hydrogen to react with one volume of oxygen to produce one volume of water vapor. Better, the whole‑number‑ratio rule seemed to hold generally. Avagadro concluded that the only way Gay‑Lussac’s rule could be general is if at any temperature and pressure, equal volumes of every kind of gas held the same number of molecules. He didn’t know what that number was, though.”

“HAW! Avagadro’s number wasn’t a number yet.”

“Yeah, it took a while to figure out. Then in 1865, Loschmidt and a couple of others started asking, “How big is a gas molecule?” Some gases can be compressed to the liquid state. The liquids have a definite volume, so the scientists knew molecules couldn’t be infinitely small. Loschmidt put numbers to it. Visualize a huge box of beetles flying around, bumping into each other. Each beetle, or molecule, ‘occupies’ a cylinder one beetle wide and the length of its mean free path between collisions. So you’ve got three volumes — the beetles, the total of all the cylinders, and the much larger box. Loschmidt used ratios between the volumes, plus density data, to conclude that air molecules are about a nanometer wide. Good within a factor of three. As a side result he calculated the number of gas molecules per unit volume at any temperature and pressure. That’s now called Loschmidt’s Number. If you know the molecular weight of the gas, then arithmetic gives you Avagadro’s number.”

“Thinking about a big box of flying, rose‑eating beetles creeps me out.”

  • Thanks to Oriole Hart for the story‑line suggestion.

~~ Rich Olcott